Thermal decomposition of ammonium nitrate

Summary The thermal decomposition reactions of ammonium nitrate (AN) are reviewed. Both neat AN and AN containing various contaminants are examined, however quantitative kinetics results are not encompassed. Also not included is the performance of AN as the oxidizer in rocket propellants or in explosives such as ANFO. The review is intended to be the most comprehensive review of decomposition reactions of AN since Berthelot's treatise of 1892. Despite hundreds of papers on the topic that have appeared in the intervening years, understanding of decomposition mechanisms remains only modestly more complete than it was in Berthelot's day. However, some additional reaction steps and mechanisms have been identified and these are discussed. Explosions of AN most commonly involve fire as the proximate cause, yet chemical‐mechanism research on the topic is nil. A modest number of studies have explored the potentiation of AN decomposition by organic contaminants. These have, thus far, not produced guidance useful for promoting of safety from fire‐related causes. Contamination from inorganic sources, notably chlorides is better understood and some mechanisms have been studied. The UN classification of AN as an oxidizer, instead of as an explosive, should not be interpreted literally, since AN has been associated with numerous detonation disasters.