The [Mn₂Cl₉]⁵⁻ mode of red emissive (C₄NOH₁₀)₅Mn₂Cl₉·C₂H₅OH under thermal treatment will be cleaved into [MnCl₄]²⁻ in the green emissive (C₄NOH₁₀)₂MnCl₄ with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-inorganic metal halide hybrids.
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Sun et al. (2019) studied this question.
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