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July 1, 1988Biochemical Journal646 citationsOpen Access

The potential diagram for oxygen at pH 7

PWPaul M. Wood

Key Points

  • The aim is to present a potential diagram detailing the redox reactions of molecular oxygen at pH 7.
  • Presented reduction potentials for one-, two-, and four-electron couples involving molecular oxygen at pH 7
  • Constructed a potential diagram to visualize these reactions
  • Explained the significance of the potentials and their implications in complex systems
  • The potential diagram illustrates the successive reductions of oxygen to the superoxide radical, H2O2, hydroxyl radical, and water
  • Each redox potential is described, showing significant involvement in the production of hydroxyl radical by Fe3+ and H2O2
  • The diagram facilitates understanding of complex biochemical systems involving these compounds

Abstract

Successive one-electron reductions of molecular oxygen yield the superoxide radical (O2-) H2O2, the hydroxyl radical (OH) and water. Redox potentials at pH 7 for one-, two- and four-electron couples involving these states are presented as a potential diagram. The significance of each of these potentials is explained. The complete potential diagram enables complex systems to be rationalized, such as production of OH by H2O2 plus Fe3+.

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Cite This Study

Paul M. Wood (1988) studied this question.

synapsesocial.com/papers/69dd70982f737f012599bf64https://doi.org/10.1042/bj2530287
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