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March 10, 2007The Journal of Physical Chemistry B548 citations

Application of Hole Theory to Define Ionic Liquids by their Transport Properties

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AAAndrew P. AbbottRHRobert C. HarrisKRKarl S. Ryder

Key Points

  • Determine the compositional boundaries where deep eutectic mixtures exhibit true ionic liquid behavior using hole theory.
  • Measured conductivity, viscosity, density, and surface tension of glycolic mixtures with choline chloride across a 0 to 0.33 mole fraction range.
  • Fitted measured transport properties to hole theory models to identify the onset of dominant hole-mediated charge mobility.
  • Demonstrated that the point where measured conductivity matches theoretical hole theory values defines the transition to dominant hole mobility.
  • Identified that this mechanistic transition occurs at a choline chloride mole fraction of approximately 0.2 for ethylene glycol and butanediol mixtures.

Abstract

Eutectic mixtures of quaternary ammonium salts with Lewis or Brønsted acids have been described as ionic liquid, but doubt exists over the compositional range for which this description is valid. In the current work, the conductivity, viscosity, density, and surface tension of a number of glycolic mixtures with choline chloride are measured over the mole fraction range 0 to 0.33. The data are fitted to hole theory, and it is proposed that the composition at which the measured conductivity matches the theoretical value is the point at which hole mobility becomes the dominant mechanism for charge mobility. For the mixtures of ethylene glycol and butanediol, this occurs at a ChCl mole fraction of approximately 0.2.

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Cite This Study

Abbott et al. (2007) studied this question.

synapsesocial.com/papers/69de7fe06e50a6aba3e93fd1https://doi.org/10.1021/jp0671998
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