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Palladium-catalyzed transfer semihydrogenation of alkynes using H₂O as the hydrogen source and Mn as the reducing reagent is developed, affording cis- and trans-alkenes selectively under mild conditions. In addition, this method provides an efficient way to access various cis-1,2-dideuterioalkenes and trans-1,2-dideuterioalkenes by using D₂O instead of H₂O.
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Zhao et al. (2019) studied this question.
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