From Statistical Mixtures to Structural Insights: Characterisation of Heterometallic M 4 L 6 8+ Coordination Cages using High Resolution Ion Mobility Mass Spectrometry

Key Points

• This research aims to characterize heterometallic coordination cages using advanced mass spectrometry techniques.
• Utilized high-resolution ion mobility mass spectrometry to analyze coordination cages.
• Focused on identifying structural differences between substrates.
• Compared multiple metal-ligand arrangements for detailed analysis.
• Successfully distinguished between various substrates based on their structural features.
• Revealed intricate details of the three-dimensional cavities in coordination cages.
• Demonstrated that subtle variations in structure impact binding and recognition.