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April 15, 2026Chemical Communications2 citations

Intercalation-Enabled Reversible Disorder and Efficient Iodine Capture in a Two-Dimensional Metal-Organic Frameworks

RXRuize XieCentral South UniversityHJHaoqing JiaCentral South UniversityPYPeng YeCentral South University

Key Points

  • The aim is to explore intercalation-induced order-disorder transitions in two-dimensional metal-organic frameworks and their capacity for iodine capture.
  • Investigated the intercalation process under mild conditions
  • Analyzed changes in structure and interactions within the framework
  • Evaluated iodine insertion and release dynamics
  • Observed reversible order-disorder transitions upon iodine intercalation
  • Demonstrated efficient iodine capture due to weak interlayer interactions
  • Highlight potential applications in gas storage and separation

Abstract

We demonstrate intercalation-induced reversible order-disorder transitions in a two-dimensional metal-organic framework. Enabled by exceptionally weak interlayer interactions, iodine reversibly inserts into the interlayer region under mild conditions, triggering pronounced pronounced...

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Cite This Study

Xie et al. (2026) studied this question.

synapsesocial.com/papers/69df2c50e4eeef8a2a6b15c2https://doi.org/10.1039/d6cc02022d
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