Dual Cocatalysts in TiO₂ Photocatalysis

Semiconductor photocatalysis is recognized as a promising strategy to simultaneously address energy needs and environmental pollution. Titanium dioxide (TiO₂ ) has been investigated for such applications due to its low cost, nontoxicity, and high chemical stability. However, pristine TiO₂ still suffers from low utilization of visible light and high photogenerated-charge-carrier recombination rate. Recently, TiO₂ photocatalysts modified by dual cocatalysts with different functions have attracted much attention due to the extended light absorption, enhanced reactant adsorption, and promoted charge-carrier-separation efficiency granted by various cocatalysts. Recent progress on the component and structural design of dual cocatalysts in TiO₂ photocatalysts is summarized. Depending on their components, dual cocatalysts decorated on TiO₂ photocatalysts can be divided into the following categories: bimetallic cocatalysts, metal-metal oxide/sulfide cocatalysts, metal-graphene cocatalysts, and metal oxide/sulfide-graphene cocatalysts. Depending on their architecture, they can be categorized into randomly deposited binary cocatalysts, facet-dependent selective-deposition binary cocatalysts, and core-shell structural binary cocatalysts. Concluding perspectives on the challenges and opportunities for the further exploration of dual cocatalyst-modified TiO₂ photocatalysts are presented.