Advances in Bi2WO6-Based Photocatalysts for Degradation of Organic Pollutants

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With the rapid development of modern industries, water pollution has become an urgent problem that endangers the health of human and wild animals. The photocatalysis technique is considered an environmentally friendly strategy for removing organic pollutants in wastewater. As an important member of Bi-series semiconductors, Bi₂WO₆ is widely used for fabricating high-performance photocatalysts. In this review, the recent advances of Bi₂WO₆-based photocatalysts are summarized. First, the controllable synthesis, surface modification and heteroatom doping of Bi₂WO₆ are introduced. In the respect of Bi₂WO₆-based composites, existing Bi₂WO₆-containing binary composites are classified into six types, including Bi₂WO₆/carbon or MOF composite, Bi₂WO₆/g-C₃N₄ composite, Bi₂WO₆/metal oxides composite, Bi₂WO₆/metal sulfides composite, Bi₂WO₆/Bi-series composite, and Bi₂WO₆/metal tungstates composite. Bi₂WO₆-based ternary composites are classified into four types, including Bi₂WO₆/g-C₃N₄/X, Bi₂WO₆/carbon/X, Bi₂WO₆/Au or Ag-based materials/X, and Bi₂WO₆/Bi-series semiconductors/X. The design, microstructure, and photocatalytic performance of Bi₂WO₆-based binary and ternary composites are highlighted. Finally, aimed at the existing problems in Bi₂WO₆-based photocatalysts, some solutions and promising research trends are proposed that would provide theoretical and practical guidelines for developing high-performance Bi₂WO₆-based photocatalysts.