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April 18, 2026Advanced ScienceOpen Access

Zero Thermal Expansion and Local Structure in K x Mn x Fe 2‐ x Mo 3 O 12 ‐Based Materials

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Authors

GHGongsen HeZhengzhou UniversityYQYongqiang QiaoMinistry of EducationSZShibo ZhaoMinistry of Education

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Overview

Demonstrates zero thermal expansion in KMnFeMo3O12, highlighting its engineering applications.

Key Points

  • The aim is to explore zero thermal expansion (ZTE) in single-phase materials by adjusting composition.
  • Designed KxMnxFe2-xMo3O12 by varying the doping ratio of KMn
  • Utilized synchrotron X-ray diffraction for structural analysis
  • Employed neutron pair distribution function and density functional theory calculations
  • Conducted Raman spectroscopy to investigate thermal expansion mechanisms
  • Achieved ZTE in KMnFeMo3O12 with a thermal expansion coefficient of 0.51 × 10−6 K−1 (100–800 K)
  • Identified monoclinic distortion in local structure despite hexagonal macroscopic structure
  • Observed low emissivity in the 1–2.5 µm near-infrared band

Cite This Study

He et al. (2026) studied this question.

synapsesocial.com/papers/69e3209340886becb653f9c4https://doi.org/10.1002/advs.75304
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