PulseExploreJournal ClubDebatesTrendingResearchersJournals
Instagram
HomeExploreJournal ClubTrending
Synapse
⌘+K
Synapse
April 19, 2026Chemical Science5 citationsOpen Access

Photoinduced deacylative epoxidation of ketone derivatives with allylic peroxides

JLJiangtao LinMZMingqian ZhouZLZiyang Li

Key Points

  • This research aims to explore a novel method for deacylative radical epoxidation of ketones using allylic peroxides.
  • Utilized allylic peroxides to induce epoxidation of ketones.
  • Employed photoinduced conditions for the reaction.
  • Investigated the formation of fused epoxides from pro-aromatic dihydroquinazolinones.
  • Successfully produced fused epoxides from ketone derivatives.
  • Demonstrated efficiency of the alternative deacylative pathway.
  • Observed significant radical cyclization leading to desired products.

Abstract

We report an alternative deacylative radical epoxidation of ketones using allylic peroxides to produce fused epoxides via the photoinduced radical cyclization of ketone-derived pro-aromatic dihydroquinazolinones.

Ask AI
Helpful
Bookmark
Share
View Full Paper

Cite This Study

Lin et al. (2026) studied this question.

synapsesocial.com/papers/69e4739a010ef96374d8f5d5https://doi.org/10.1039/d6sc00898d
Ask AI
Helpful
Bookmark
Share
View Full Paper