A green chemistry approach has been furnished for photochemical deposition of alpha-MnO2 nanorods onto the surface of functionalized polystyrene beads through immobilization of MnO4- in alkaline condition under visible light. Then the composite material was exploited as a fruitful and novel solid-phase catalyst for the one-step and facile synthesis of amide compounds from nitriles under visible light in weakly basic medium.
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Jana et al. (2007) studied this question.
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