Understanding the Effect of Water on CO₂ Adsorption

Carbon capture from large sources and ambient air is one of the most promising strategies to curb the deleterious effect of greenhouse gases. Among different technologies, CO₂ adsorption has drawn widespread attention mostly because of its low energy requirements. Considering that water vapor is a ubiquitous component in air and almost all CO₂-rich industrial gas streams, understanding its impact on CO₂ adsorption is of critical importance. Owing to the large diversity of adsorbents, water plays many different roles from a severe inhibitor of CO₂ adsorption to an excellent promoter. Water may also increase the rate of CO₂ capture or have the opposite effect. In the presence of amine-containing adsorbents, water is even necessary for their long-term stability. The current contribution is a comprehensive review of the effects of water whether in the gas feed or as adsorbent moisture on CO₂ adsorption. For convenience, we discuss the effect of water vapor on CO₂ adsorption over four broadly defined groups of materials separately, namely (i) physical adsorbents, including carbons, zeolites and MOFs, (ii) amine-functionalized adsorbents, and (iii) reactive adsorbents, including metal carbonates and oxides. For each category, the effects of humidity level on CO₂ uptake, selectivity, and adsorption kinetics under different operational conditions are discussed. Whenever possible, findings from different sources are compared, paying particular attention to both similarities and inconsistencies. For completeness, the effect of water on membrane CO₂ separation is also discussed, albeit briefly.