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April 19, 2026European Journal of Inorganic Chemistry

Pentafluoroethylated Chalcogenophosphates: Synthesis and Characterization

Lukas Hartmann Julia Bader Hans‐Georg Stammler Berthold Hoge Mira Keßler

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Key Points

This work aims to synthesize and characterize unique five-coordinated P(V)-phosphates.
Synthesize oxophosphate and thiophosphate through oxidation of phosphazenium phosphoranide.
Prepare oxophosphate from P(C2F5)3F2 as a precursor and explore reactions with water.
Conduct computational studies to describe oxophosphate and thiophosphate using Lewis structures.
Successful synthesis of rare five-coordinated P(V)-phosphates was achieved.
Oxonium salt of hydroxophosphate was formed upon reacting with water.
Computational studies aided in illustrating the structures of the synthesized phosphates.

Implication

Novel chalcogenophosphates were synthesized and characterized, indicating potential new compounds in phosphorus chemistry.

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Cite This Study

Hartmann et al. (2026) studied this question.

synapsesocial.com/papers/69e713fdcb99343efc98d6a7 https://doi.org/10.1002/ejic.202500634

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