Novel Anderson-type polyoxomanganotungstate clusters with the β-isomer structure, [{R₁R₂C(CH₂O)₂}MnIVW₆O₂₂]⁶⁻, were synthesized and monofunctionalized with derivatives of 1,3-propanediol via a one-pot strategy, and show unprecedented coordination activity as non-lacunary polyoxotungstate clusters and could have potential in the future construction of POM-frameworks.
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Li et al. (2021) studied this question.
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