Demonstrates protonation-controlled fluorescence switching in 2,7-diazatriptycene, suggesting potential applications in molecular sensors.
An unexplored 2,7-diazatriptycene exhibits protonation-controlled ternary fluorescence switching (on/off, cyan/violet) through modulation of through-space conjugation. Protonation also reorganizes crystal packing from herringbone assemblies to charge-segregated layered structures.
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Inoue et al. (2026) studied this question.
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