This synthesis demonstrates umpolung reactivity to form functionalized oxazoles, highlighting a novel approach.
We report the synthesis of functionalized oxazoles via an umpolung reactivity of N-sulfonylhydrazones and imino esters. The reaction involves light-induced N–S bond cleavage of N-sulfonylhydrazones to produce nucleophilic diazo intermediates...
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Mohammad et al. (2026) studied this question.
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