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April 25, 2026Chemical Communications0 citations

Supramolecular Glass Formation by Arene–Perfluoroarene Pairing of Three-Dimensional Macrocycles

KOKatsuto OnishiSOShunsuke OhtaniKKKenichi Kato

Key Points

  • This research aims to explore the conditions for supramolecular glass formation using specific macrocycle combinations.
  • Mixed two crystalline pillar[6]arenes with benzyl and pentafluorobenzyl substituents.
  • Investigated the glass formation despite the absence of a melting point in both compounds.
  • Successfully achieved supramolecular glass formation by the arene–perfluoroarene pairing.
  • Attributed glass formation to interactions between the substituted components.

Abstract

We report supramolecular glass formation by mixing two crystalline pillar6arenes bearing benzyl and pentafluorobenzyl substituents, even though neither compound exhibited a melting point. The glass formation was attributed to arene–perfluoroarene...

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Cite This Study

Onishi et al. (2026) studied this question.

synapsesocial.com/papers/69ec5b0688ba6daa22dac9c1https://doi.org/10.1039/d6cc01163b
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