The Characterisation and Reactivity of a Rh III η 1 -σ-Alkane Complex and the Role of a Structurally Responsive Phosphine Ligand in Solid-State Molecular Organometallic Chemistry

Key Points

• This research aims to investigate the reactivity and properties of a rhodium complex with a specific phosphine ligand.
• Combined experimental and computational techniques.
• Studied single-crystal to single-crystal addition of H2 to a rhodium complex.
• Analyzed the role of phosphine ligand in the reactivity of the complex.
• Confirmed the formation of a Rh(III) η1-σ-alkane complex after H2 addition.
• Demonstrated the influence of the structurally responsive phosphine ligand on reactivity.
• Provided insights into solid-state molecular organometallic chemistry dynamics.