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April 29, 2026Green Chemistry1 citations

Triacetic acid lactone conversion to methylene-δ-caprolactone: a renewable monomer for bio-based circular polymer synthesis

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COCamilo A. Ortega-VegaBLBowei LiuFEFrancesca D. Eckstrom

Key Points

  • This research aims to explore the conversion of triacetic acid lactone into a renewable monomer for circular polymer applications.
  • Developed a multistep catalytic strategy
  • Utilized bio-derived triacetic acid lactone (TAL)
  • Synthesized poly(α-methylene-δ-caprolactone) (PMCL)
  • PMCL exhibits higher heat resistance compared to traditional PMMA
  • Demonstrated chemical recyclability of the synthesized polymer
  • Provides a sustainable alternative for polymer applications

Abstract

We report a multistep catalytic strategy for converting bio-derived triacetic acid lactone (TAL) into poly(α-methylene-δ-caprolactone) (PMCL), a sustainable PMMA analogue with higher heat resistance and demonstrated chemical recyclability.

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Cite This Study

Ortega-Vega et al. (2026) studied this question.

synapsesocial.com/papers/69f19ff5edf4b468248069f3https://doi.org/10.1039/d6gc01148a
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