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April 30, 2026Energy & Fuels2 citations

Graphene Oxide-Stabilized Polymeric Nanofluids for Enhanced Oil Recovery

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GRG RaoNPNilanjan PalAMAjay Mandal

Key Points

  • This research aims to evaluate the efficacy of graphene oxide-stabilized polymeric nanofluids for enhanced oil recovery (EOR).
  • Synthesized graphene oxide nanosheets via modified Hummers method
  • Formulated polymeric nanofluids with hydroxyethyl cellulose solutions
  • Evaluated rheological properties under varying temperatures and shear rates
  • Conducted core flooding experiments to assess oil recovery performance
  • Performed spectroscopic analysis including FTIR and UV spectroscopy
  • Achieved tertiary oil recovery of 24.76% OOIP with GO nanofluids
  • Demonstrated significant enhancement in rheological properties due to synergistic interactions
  • Showed qualitative shift towards more water-wet conditions in sandstone
  • Validated intermolecular interactions through FTIR and DSC analyses
  • Indicated scalability and cost-effectiveness of the developed EOR agents

Abstract

Developing advanced nanofluids with tailored rheological properties is crucial for optimizing enhanced oil recovery (EOR) techniques. This study investigates graphene oxide (GO) nanosheet-assisted polymeric nanofluids and evaluates their potential for EOR applications. GO nanosheets were synthesized using the modified Hummers method and characterized using FTIR, UV spectroscopy, XRD, and Raman spectroscopy analysis. Polymeric nanofluids were formulated by dispersing GO nanosheets into hydroxyethyl cellulose (HEC) solutions, and their rheological properties were evaluated at varying shear rates and temperatures to simulate reservoir conditions. The results showed that the addition of a low concentration of GO (50 ppm) significantly enhanced the rheological properties of HEC polymer solutions due to synergistic interactions between GO nanosheets and polymer chains that form three-dimensional networks via hydrogen bonding. These intermolecular interactions were further validated through FTIR and DSC analyses. Additionally, qualitative changes in the sandstone rock’s wettability were evaluated using spectroscopic techniques, revealing a shift toward more water-wet conditions. Core flooding experiments demonstrated superior performance of the polymeric nanofluid, achieving a tertiary oil recovery of 24.76% OOIP compared to 17.93% for polymer flooding. Furthermore, preliminary industrial feasibility and economic analyses suggest the scalability and cost-effectiveness of the developed system. Overall, this study highlights the potential of GO–HEC nanofluids as efficient and viable EOR agents.

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Cite This Study

Rao et al. (2026) studied this question.

synapsesocial.com/papers/69f2a49d8c0f03fd67763aachttps://doi.org/10.1021/acs.energyfuels.6c00569
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