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April 30, 2026ChemSusChem0 citations

Microwave Quasi‐Solid State to Construct Boron‐Doped Black TiO 2 Supported Ru as Advanced Electrocatalyst for Seawater Hydrogen Generation

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YSYuanzong ShenQingdao University of Science and TechnologyELEnze LiQingdao University of Science and TechnologySFSiyuan FengSouthwest University

Key Points

  • This research aims to develop an efficient electrocatalyst for hydrogen generation using a microwave-assisted method.
  • Utilized a microwave quasi-solid approach to synthesize boron-doped black TiO2 supported Ru
  • Analyzed electrocatalyst performance in 1 M KOH and alkaline seawater environments
  • Investigated the effects of oxygen vacancies and metal-support interactions on catalyst stability
  • Achieved overpotentials of 39 mV in 1 M KOH and 61 mV in alkaline seawater for hydrogen evolution
  • Demonstrated excellent activity and stability of the boron-doped black TiO2-Ru catalyst
  • Showed improved energy band structure and additional active sites due to boron incorporation

Abstract

) is achieved through rapid (40 s) microwave quasi-solid approach. The incorporation of B modulates the energy band structure of the electrocatalyst, creating additional active sites, and then favors the water dissociation and following hydrogen desorption. The presence of oxygen vacancy defects and metal-support interactions (MSI) lead to satisfactory stabilization of the catalysts. These effects collectively contributed to the superior performance in 1 M KOH and alkaline seawater for the hydrogen evolution reaction (HER) with small overpotentials of 39 and 61 mV, respectively, which also demonstrates excellent activity and stability. This work presents a novel microwave-assisted strategy for constructing metal oxide supported low-content noble metals for energy conversion and storage applications.

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Cite This Study

Shen et al. (2026) studied this question.

synapsesocial.com/papers/69f2f19c1e5f7920c63873efhttps://doi.org/10.1002/cssc.70672
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