This research demonstrates how positional isomerism improves electronic properties in carbon nanohoops, suggesting new design strategies.
inclusion complexes. Photophysical studies and DFT calculations reveal that the relative positioning of the pyridinium units influences the optical properties and HOMO-LUMO gaps of these donor-acceptor nanohoops. This work demonstrates that positional isomerism on the nanohoop framework is an effective strategy for tuning electronic properties and expands the design space for functionalized carbon nanohoops.
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Hu et al. (2026) studied this question.
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