Demonstrates the unique reactivity of anionic vanadium alumanyl, suggesting insights into metal bond characteristics.
Al nucleus. Furthermore, V K-edge XANES and XPS data revealed the oxidation states of the V and Al centers, highlighting the reduced nature of both metal centers. Reactivity studies revealed the dissociation of the anionic alumanyl ligand from the V center even in the presence of the multiple V─Al bond character, in stark contrast to the reactivity of the neutral analogue, as supported by a DFT-based mechanistic study.
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Zatsepin et al. (2026) studied this question.
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