January 1, 2011Open Access

Stability improvement of Cu3(BTC)2 metal–organic frameworks under steaming conditions by encapsulation of a Keggin polyoxometalate

DMDanilo MustafaUniversidade de São Paulo EBEric BreynaertInstitute of Catalysis and Petrochemistry SBSneha R. BajpeSymbiosis International University

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Abstract

Cu(3)(BTC)(2) with an incorporated Keggin polyoxometalate was demonstrated to be stable under steaming conditions up to 483 K, while the isostructural HKUST-1 degrades and transforms into Cu(2)OH(BTC)(H(2)O)(n)·2nH(2)O from 343 K onwards.

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Mustafa et al. (Sat,) studied this question.

synapsesocial.com/papers/69f47eb5d241a6280ce26404 https://doi.org/https://doi.org/10.1039/c1cc12341f

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