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May 3, 20260 citations

Metal-free Minisci C-H alkylation of hydrazones using aldehydes: an unexpected route to hydrazone-containing pyrimidine derivatives.

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ATAtefeh TirehdastFerdowsi University of MashhadVSVolodymyr SemeniuchenkoUniversity of OttawaASAli ShiriFerdowsi University of Mashhad

Key Points

  • The aim is to explore a metal-free Minisci C-H alkylation process for synthesizing hydrazone-containing pyrimidine derivatives using aldehydes.
  • Utilized aldehydes for C-H alkylation of hydrazones
  • Implemented a method involving trifluoroacetic acid
  • Focused on synthesizing structurally diverse heterocyclic compounds.
  • Successfully developed a scalable metal-free method for the synthesis of pyrimidine derivatives
  • Demonstrated practicality for accessing a variety of structurally heterocyclic compounds.

Abstract

and trifluoroacetic acid (TFA). This method provides a practical and scalable approach to accessing structurally heterocyclic compounds of various classes.

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Cite This Study

Tirehdast et al. (2026) studied this question.

synapsesocial.com/papers/69f6e6648071d4f1bdfc711dhttps://doi.org/10.1039/d6ra01465h
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