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January 1, 2026Dalton TransactionsOpen Access

Activation of N2O, CO2 , and CO at a sterically protected phosphorus center

John Wenger William J. Rowe Meera Mehta

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Key Points

The aim is to explore activation pathways of N2O, CO2, and CO at a sterically protected phosphorus center.
Utilized a potassium phosphanide salt [K(crypt)][(MsFluInd)PH] for functionalization.
Examined the sterically encumbered phosphorus precursor to enable activation.
Analyzed varied activation mechanisms for multiple gases.
Identified distinct activation pathways for N2O, CO2, and CO.
Confirmed functionalization enhances reactivity at the phosphorus center.
Showed that steric protection influences reactivity dynamics.

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Implication

Demonstrates varied activation pathways for N2O, CO2, and CO via phosphorus functionalization, suggesting new chemical processes.

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Cite This Study

Wenger et al. (2026) studied this question.

synapsesocial.com/papers/69f6e6968071d4f1bdfc759b https://doi.org/10.1039/d6dt00986g

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