Impacts of Coal Resource Development on Naphthenic Acids in Water Resources: A Case Study from the Shenfu Open-Pit Coalfield, China

Coal resource exploitation may alter hydrogeological conditions and influence the occurrence and migration of coal-derived organic contaminants in mining regions. Among these contaminants, naphthenic acids (NAs) have received increasing attention, whereas their occurrence and environmental behavior in coal mining areas remain insufficiently understood. For the first time in an open-pit coal mining setting, this study systematically investigated the concentrations and molecular compositions of NAs in surface water, groundwater, and source-related water samples from the Shenfu Coalfield, a representative mining area in China. NAs were detected in all samples, with concentrations exhibiting clear spatial variability. Groundwater consistently contained substantially higher NA levels than surface water, and elevated concentrations in downstream river reaches coincided spatially with groundwater discharge zones, identifying groundwater as a key reservoir and transport pathway for NAs in the mining-affected watershed. Principal component analysis further revealed compositional similarities among groundwater, coal-washing wastewater, and certain surface-water samples, indicating contributions from both coal-bearing strata and coal-processing activities. These findings highlight the necessity of incorporating NAs into routine mine-water monitoring and groundwater protection programs in open-pit coal mining regions.