Unsymmetrical azines were obtained via the reaction of hydrazonoyl halides with methyl dithioate. Hydrazonoyl halides reacted with phenyldithiocarbamate and phenylthiourea to give 2-anilino-2,3-dihydro-1,3,4-thiadiazoles and 2-anilino-5-phenylazothiazoles depending on the hydrazonoyl halides used.
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Zohdi et al. (1998) studied this question.
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