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Besides its capability to gelate various organic solvents, dicyclohexyl ammonium 4-chlorocinnamate 1 is shown to perform selective gelation of oil from oil/water mixtures. While the corresponding 3-chloro derivative 2 is an excellent gelator of nonpolar organic solvents, 2-chloro derivative 3 turned out to be a nongelator.
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Trivedi et al. (2003) studied this question.
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