The spin-crossover equilibrium midpoint temperature (T1/2) in [Fe(3-bpp)2]X2 (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) varies from 259 K when X− = BPh4− to 277 K when X− = Br−, at 10 mM concentrations in an acetone–water solvent mixture.
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Barrett et al. (2014) studied this question.
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