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May 10, 2026Journal of the American Chemical Society4 citations

Reactive Ions in Aqueous Electrospray Microdroplet Experiments Originate from Electrical Discharge

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CZChong ZhangJVJake P. VioliCHChristopher S. Hansen

Key Points

  • The research aims to understand how reactive ions in electrospray microdroplets are influenced by electrical discharge processes.
  • Conducted experiments on ion distributions from aqueous electrospray microdroplets.
  • Analyzed the effects of electrical discharge on droplet-phase reactivity.
  • Implemented experimental controls to differentiate between discharge-driven processes and droplet reactions.
  • Ion distributions were significantly affected by electrical discharge processes.
  • Identifying discharge-driven processes was crucial for correctly assigning reaction mechanisms.

Abstract

ion distributions. These findings highlight the importance of experimental controls that distinguish discharge-driven processes from droplet-phase reactivity when assigning reaction mechanisms.

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Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/6a00205ec8f74e3340f9b3dfhttps://doi.org/10.1021/jacs.6c05890
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