Reactive Ions in Aqueous Electrospray Microdroplet Experiments Originate from Electrical Discharge

Chong Zhang; Jake P. Violi; Christopher S. Hansen; William A. Donald

doi:10.1021/jacs.6c05890

May 7, 2026Journal of the American Chemical Society

Reactive Ions in Aqueous Electrospray Microdroplet Experiments Originate from Electrical Discharge

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Key Points

The research aims to understand how reactive ions in electrospray microdroplets are influenced by electrical discharge processes.
Conducted experiments on ion distributions from aqueous electrospray microdroplets.
Analyzed the effects of electrical discharge on droplet-phase reactivity.
Implemented experimental controls to differentiate between discharge-driven processes and droplet reactions.
Ion distributions were significantly affected by electrical discharge processes.
Identifying discharge-driven processes was crucial for correctly assigning reaction mechanisms.

Implication

Evaluates ion distributions linked to electrical discharge in microdroplet experiments, highlighting important controls for understanding reactions.

Abstract

ion distributions. These findings highlight the importance of experimental controls that distinguish discharge-driven processes from droplet-phase reactivity when assigning reaction mechanisms.

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Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/6a00205ec8f74e3340f9b3df https://doi.org/10.1021/jacs.6c05890

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Reactive Ions in Aqueous Electrospray Microdroplet Experiments Originate from Electrical Discharge

Key Points

Implication

Abstract

Discussion

Cite This Study

Reactive Ions in Aqueous Electrospray Microdroplet Experiments Originate from Electrical Discharge

Key Points

Implication

Abstract

Discussion

Cite This Study

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