This work aims to construct metal-organic cages using hydrogen bond-directed foldamer preorganization for capturing challenging molecules.
Utilized hydrogen bond-directed foldamer preorganization for cage assembly.
Constructed nitrogen-enriched Pd3L6 cages.
Focused on creating confined reactive cavities for enhancing molecule capture.
Successfully demonstrated the capability of the cages to capture methyl iodide.
Achieved effective chemisorption-driven capture of specific molecules.
Abstract
. This work establishes hydrogen bond-directed foldamer preorganization as a supramolecular strategy for constructing metal-organic cages with confined reactive cavities for challenging molecule capture.