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May 10, 2026Chemistry - A European Journal0 citationsOpen Access

Precise Control of Water Adsorption Behavior in Solid Solutions of Amorphous Coordination Polymers

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HYHaruka YoshinoKYKohei YamagamiYIYuki Imamura

Key Points

  • The study aims to understand how water adsorption behaves in solid solutions of amorphous coordination polymers during transformation.
  • Utilized K-edge X-ray absorption fine structure (XAFS) techniques to analyze bond energies.
  • Investigated the amorphous-to-crystalline transition of the polymers under varying water conditions.
  • Identified slight differences in bond energies associated with water-induced transformations.
  • Confirmed a change in coordination geometry from tetrahedral to octahedral during the transformation.

Abstract

- and K-edge X-ray absorption fine structure (XAFS) techniques. Slight differences in the bond energies of bonds in the vicinity of the water-induced amorphous-to-crystalline transformation. This transformation involves a change in the coordination geometry, from tetrahedral to octahedral, through the rearrangement of CN-Co(M) bonds via cleavage/reformation, giving rise to the desirable water uptake characteristics.

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Cite This Study

Yoshino et al. (2026) studied this question.

synapsesocial.com/papers/6a00217ac8f74e3340f9c655https://doi.org/10.1002/chem.71070
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