Bivalves as a Mercury Bioindicator: A National Isotopic Survey along the Coast of South Korea

Hg (-0.35 ± 0.55‰), highlighting a sedimentary source, whereas mussels exhibited higher values (0.72 ± 0.87 and 0.09 ± 0.72‰, respectively) indicating bioaccumulation from the water column. Sulfur, carbon, and nitrogen stable isotopes suggested that such a difference was not due to feeding niches. However, Hg isotopic trajectory analysis showed that environmental conditions controlling the desorption and remobilization of sediment Hg, notably via tidal flows, were likely to drive the observed source(s). While sediment Hg is not systematically reflected in biota, bivalves, which typically display Hg pools accumulated by benthic or pelagic food webs, appear valuable for Minamata Convention biomonitoring, though their fluctuating Hg sources require careful interpretation.