A mononuclear bis(NHC)/Au(I) (NHC=N-heterocyclic carbene) cationic complex with a rigid bis(phosphane)-functionalized NHC ligand (PC(NHC)P) was used to construct linear Au3 and Ag2 Au arrays, a Au5 cluster with two intersecting crosslike Au3 arrays, and an unprecedented Cu6 complex with two parallel Cu3 arrays. The impact of metallophilic interactions on photoluminescence was studied experimentally.
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Ai et al. (2016) studied this question.
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