Selectivity Map for the Late Stages of CO and CO2 Reduction to C2 Species on Copper Electrodes

RR shows that sites with moderate coordination (5.9 < CN < 7.5) are efficient for ethylene production, with pristine Cu(100) being more active than defective surfaces such as Cu(311). In contrast, kinks and edges are more active for ethanol production, while (111) terraces are relatively inert.