A Highly Stretchable Polyacrylonitrile Elastomer with Nanoreservoirs of Lubricant Using Cyano-Silver Complexes

/polyacrylonitrile elastomer with nanoreservoirs of lubricant using cyano-silver complexes. The prepared products feature nanoconfinement structures of lubricant surrounded by polymer chains with coordination bond through chelates of cyano-silver, resulting in an enhanced stretchability of more than 600% from 2%. The elastomeric properties were investigated, and a mechanical response model was proposed, which explained the structural evolution including the polymer chain fluidity under external deformation. Also, the easy breakage and dynamic reformation of cyano-silver coordination complexes promises a strain recovery under various stretching conditions. This elastomer itself can directly work as sensors and open paths to alternative substrates for soft electronics development.