Photomineralization of Effluent Organic Phosphorus to Orthophosphate under Simulated Light Illumination

P liquid nuclear magnetic resonance spectra demonstrated that the release of orthophosphate resulted from photomineralization of OP. Furthermore, the photoproduced hydroxyl radicals (·OH) were proved to play a dominant role in the OP photomineralization. Nitrate, effluent organic matter (EfOM), and Fe(III) presented in effluent were the main chromophores for ·OH photoproduction, and their contributions to ·OH production and photomineralization of OP followed the order: nitrate > EfOM > Fe(III). Additionally, the carbonate (or bicarbonate) in the effluent and high pH were unfavorable for OP photomineralization. The present study revealed the photomineralization behavior of OP in actual effluent, suggesting that photomineralization of OP might contribute to eutrophication and may play a non-negligible role in phosphorus turnover in water bodies.