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Photo-Brook rearrangement of acyl silanes as a strategy for photoaffinity probe design | Synapse

January 1, 2022Open Access

Photo-Brook rearrangement of acyl silanes as a strategy for photoaffinity probe design

APAnnika C. S. PageUniversity of California, Berkeley SSSpencer O. ScholzAbbVie (United States)KNKatherine E. NearUniversity of California, Berkeley

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Resumen

Pr acyl silanes were shown to selectively label recombinant BRD4-BD1 and FKBP12, respectively, with minimal background. Together, these data highlight the untapped potential of acyl silanes as a novel, tunable scaffold for photoaffinity labeling.

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Page et al. (Sat,) studied this question.

synapsesocial.com/papers/6a021647e8ec6bd19dcb1c0f https://doi.org/https://doi.org/10.1039/d2sc00426g

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