December 16, 2009

Larger Spontaneous Polarization Ferroelectric Inorganic−Organic Hybrids: PbI3∞ Chains Directed Organic Cations Aggregation to Kagomé-Shaped Tubular Architecture

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Abstract

Four isostructural inorganic−organic hybrid ferroelectric compounds, assembled from achiral 3-R-benzylidene-1-aminopyridiniums (R = NO2, Br, Cl, or F for 1−4, respectively) and PbI3− anions with the chiral Kagomé-shaped tubular aggregating architecture, show larger spontaneous polarizations.

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Zhao et al. (Wed,) studied this question.

synapsesocial.com/papers/6a023ff14315194e289f45e5 https://doi.org/https://doi.org/10.1021/ja907562m

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