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Piperidine- and imidazole-based dicatoinic ionic liquids have been developed for the synthesis of zeolite Beta. Hierarchical Beta has a larger surface area and pore volume than conventional Beta. Beta derived from a dicationic ionic liquid exhibited remarkably higher catalytic activity than the conventional Beta. Experimental evidence and DFT calculations suggest that only a suitable conformation of such dicationic ionic liquids is able to form zeolite Beta (see scheme).
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Kore et al. (2011) studied this question.
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