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Supramolecular chemistry is based on weak intermolecular forces which nevertheless are of importance for chemical processes. In this report the relevance of alkyl-alkyl interactions in supramolecular assemblies is discussed. We show how hierarchically formed helicates can be used to evaluate weak interactions of alkyl groups based on solvent-supported London dispersion. In addition, the role of nano-segregation of alkyl groups in the periphery of supramolecular assemblies is described, as well as how this can be used to improve the properties of liquid-crystalline materials by controlling the alkyl-chain-mediated aggregation process.
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Giese et al. (2020) studied this question.
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