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Highlights the dual catalytic pathways in nickel-catalyzed alkylation and dimerization processes, suggesting innovative synthetic routes.
ligands along with the distinctive reductive properties of silane. Mechanistic investigations suggest that the transformation proceeds through a dual catalytic pathway involving both Ni(II)-Ni(I) and Ni(I)-Ni(II)-Ni(III) catalytic cycles.
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Mirza et al. (2026) studied this question.
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