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Crystalline materials with nanometer-sized pores (giant pores) could find many applications--for example, in catalysis and nanotechnology. Aluminosilicate materials with somewhat smaller pores long dominated the field of crystalline porous materials. However, recent advances have led to a wide chemical variety of porous materials and to larger pores. The strategies used to synthesize these materials point the way toward stable materials with giant pores.
Férey et al. (Fri,) studied this question.
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