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May 15, 2026Science Advances25 citationsOpen Access

4D printing of hierarchically porous carbon–supported high-entropy ceramic metamaterial for tunable microwave absorption

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GFGuanghui FengSWShuo WangAOAmr Osman

Key Points

  • This research aims to develop a broadband-tunable electromagnetic wave absorption material for improved performance in dynamic scenarios.
  • Developed a 4D-printed pyramidal metamaterial using hierarchically porous carbon and high-entropy ceramics.
  • Evaluated absorption performance across various configurations, including helical and load-bearing architectures.
  • Assessed tunability using thermal stimuli at 120°C.
  • Achieved an absorption bandwidth of 14.16 gigahertz with ≥90% absorption, a 98.88% enhancement over bulk materials.
  • Enabled tunable absorption from 5.24 to 18 gigahertz while maintaining reflection loss below −20 decibels.
  • Demonstrated structural adaptability through various complex configurations.

Abstract

Broadband-tunable electromagnetic wave absorption materials are critical for dynamic scenarios, such as those in wireless communication and radar systems. However, conventional absorbers are limited by narrow bandwidth and fixed postfabrication geometries. Herein, we propose a four-dimensional (4D)-printed pyramidal metamaterial comprising a hierarchically porous carbon–supported high-entropy ceramic and a shape memory elastomer. By synergizing macroscopic cavity resonances with microscopic defect-induced polarizations, the metamaterial delivers an absorption bandwidth of 14.16 gigahertz (≥90% absorption), representing a 98.88% enhancement over its bulk counterpart. In addition, it enables spatial reconfiguration via a moderate thermal stimulus (120°C), achieving tunable absorption across 5.24 to 18 gigahertz while maintaining reflection loss below −20 decibels (≥99% absorption). The base material’s adaptability to complicated configurations is demonstrated by helical, origami-inspired, and load-bearing architectures. This work paves the way for metamaterial absorbers with multiple configurations and shape reversibility, advancing their applications in multispectral and intelligent adaptive systems.

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Cite This Study

Feng et al. (2026) studied this question.

synapsesocial.com/papers/6a06b8f8e7dec685947ab7a3https://doi.org/10.1126/sciadv.aed0172
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