Six aromatic aldehydes (benzaldehyde, cinnamaldehyde (trans) α‐naphtaldehyde, β‐naphtaldehyde, 9‐phenanthrenaldehyde and 9‐anthracenaldehyde) have been polarographically investigated in Britton ‐ Robinson buffers containing 50% ethanol, over the range of pH = 2 t o pH = 13. It is shown that the characteristic half‐wave potentials and E and E * may both be calculated a priori by zero th order MO theory.
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Schmid et al. (1954) studied this question.
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