Polygonatiin (IV), C33H40 5H2O, mp 215-217°, a new C-glucosylflavone, was isolated from the leaves of Polygonatum odoratum (MILL.) DRUCE var. pluriflorum (MIQ.) OHWI (Liliaceae) together with oosmosiin (I), vitexin (II), vitexin 2"-O-glucoside (III), and saponarin (V). The structure of polygonatiin was determined as vitexin 2"-O-sophoroside by chemical degradation and spectral measurements.
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Morita et al. (1976) studied this question.