Holding onto Lots of Hydrogen: A 12‐Hydride Rhodium Cluster That Reversibly Adds Two Molecules of H₂

H wie Hülle: Die Cluster [Rh6(PR3)6H12][BArF4]2 (R=Cyclohexyl, iPr; siehe Bild: Rh rosa, P orange) nehmen unter Standardbedingungen (1 atm H2, 298 K) reversibel 2 H2-Moleküle auf. Dabei entstehen diskrete oktaedrische Cluster, die von 16 Hydridliganden umhüllt sind. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2005/z502221_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.