Radical‐Type Reactivity and Catalysis by Single‐Electron Transfer to or from Redox‐Active Ligands

Controlled ligand-based redox-activity and chemical non-innocence are rapidly gaining importance for selective (catalytic) processes. This Concept aims to provide an overview of the progress regarding ligand-to-substrate single-electron transfer as a relatively new mode of operation to exploit ligand-centered reactivity and catalysis based thereon.